Choose the member of each set that has the higher solubility
in water. Briefly, explain your answer.
a) CH3CH2CH3 or CH3OCH3
Answer:
To begin to answer this question we need to determine the most
important intermolecular attractive force for both of these compounds. To assign
the IMAF we need to know if the compound is polar or nonpolar.
So first determine the polarity of CH3CH2CH3
or CH3OCH3
The Lewis structure for CH3CH2CH3
is;
Another view of this structure uses a ball-and-stick model;
The central atoms have no lone pairs and all of the terminal
atoms are the same so the type of IMAF are dispersion forces for propane.
The Lewis structure for CH3OCH3 is;
Another view of this structure uses a ball-and-stick model;
The central oxygen atom has two lone pairs so the type of IMAF
are dipole-dipole and dispersion forces for propane.
Now we can reach a conclusion which of the two compounds is more
soluble.
Dimethyl ether, CH3OCH3, is more soluble
in water than propane, CH3CH2CH3. Since dimethyl
ether is polar it will be more soluble in water (a polar solvent) compared to
propane a nonpolar substance.